Lives listing by occupation: diplomat
- Solaro di Breglio, Roberto Ignazio (died 1765), Italian courtier, diplomat
- Solaro di Moretta, Ignazio, marchese del Borgo (died 1743), Italian diplomat
- Soulavie, Jean Louis Giraud (born 1752–died 1813), French politician, revolutionary, diplomat, author
- Sousa Coutinho, Domingos António de, 1st marquis of Funchal (born 1760–died 1833), Portuguese aristocrat, diplomat, politician, colonial governor
- Southwell, Sir Robert (born 1635–died 1702), Irish diplomat, civil servant, academician, politician, member of Parliament
- Spanheim, Ezechiel von, Freiherr von Spanheim (born 1629–died 1710), Swiss diplomat, scholar, classicist, numismatist
- Staël von Holstein, Erik Magnus de, baron de Staël von Holstein (born 1749–died 1802), Swedish diplomat, courtier
- Stanhope, James, 1st Earl Stanhope (born 1673–died 1721), English army officer, diplomat, politician, member of Parliament
- Stanhope, Philip (born 1732–died 1768), English diplomat
- Stanhope, Philip Dormer, 4th earl of Chesterfield (born 1694–died 1773), English politician, diplomat
- Stanhope, William, 1st earl of Harrington (born 1683–died 1756), English diplomat, politician, member of Parliament
- Stanyan, Abraham (born 1672–died 1732), English diplomat
- Starhemberg, Johann Georg Adam von, graf von Starhemberg (born 1724–died 1807), Austrian aristocrat, courtier, diplomat, civil servant
- Staunton, Sir George Leonard, baronet (born 1737–died 1801), Irish physician, plantation-owner, diplomat, East India Company official, academician
- Stepney, George (born 1663–died 1707), English diplomat, poet, academician
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