Lives listing by occupation: diplomat
- Venier, Francesco (flourished 1736–1790), Italian diplomat
- Verninac de Saint-Maur, Raimond (born 1761–died 1822), French lawyer, poet, diplomat
- Vertmont, M. — de (flourished 1744–1755), French diplomat
- Veselovsky, Avram Pavlovich (born 1685–died 1782), Russian diplomat, conspirator
- Veselovsky, Fedor Pavlovich (born after 1687), Russian diplomat, legal author, university principal
- Vintimille, Charles François de (born 1738–died 1796), French diplomat, patron
- Vorontsov, Prince Aleksandr Romanovich (born 1741–died 1805), Russian aristocrat, diplomat, civil servant
- Voyer de Paulmy, Marc Antoine René de, marquis de Paulmy & de Voyer (born 1722–died 1787), French government minister, diplomat, bibliophile, collector
- Wackerbarth, Joseph Anton Gabaleon von, graf von Wackerbarth (born 1685–died 1761), German army officer, courtier, diplomat, civil servant
- Walpole, Horatio, 1st Baron Walpole of Wolterton (born 1678–died 1757), English diplomat, government minister, politician, member of Parliament
- Warden, David Bailie (born 1772–died 1845), Irish midwife, diplomat, author, journalist, science-writer, scholar
- Watkins, Henry (flourished 1684–1712), English lawyer, diplomat
- Wellesley, Richard Colley, 1st Marquess Wellesley (born 1760–died 1842), Irish aristocrat, colonial governor, diplomat, politician, member of Parliament
- Wentworth, Thomas, 1st earl of Strafford [2nd creation] (born 1672–died 1739), English army officer, diplomat
- Whitefoord, Caleb (born 1734–died 1810), Scottish wine-merchant, poet, diplomat, academician, tradesman
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